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tert-Butylphenylboronic acid CAS 123324-71-0 4-(tert-Butyl)phenylboronic acid p-tert-Butylphenylboronic acid
Product Identification
Chemical name: 4-tert-Butylphenylboronic acid
Synonyms: 4-(tert-Butyl)phenylboronic acid, p-tert-Butylphenylboronic acid
CAS No.: 123324-71-0
Molecular formula: C10H15BO2
Molecular weight: 178.04
Melting point: 193-199 oC
Specification
Appearance: White to off white solid
Purity: 98.50%min by HPLC
Loss on drying: 0.50%max
Package
Regular Packing: N.W 25kg/fiber drum
Sample Packing: 0.1kg-1kg foil bag or under request
Transportation Information
Classification:&©|160;
&©|160; &©|160; &©|160;Non dangerous goods
HS Code: 2920900090
Application
Enantioselective Oxidative Homocoupling and Cross-Coupling of 2-Naphthols Catalyzed by Chiral Iron Phosphate Complexes
Novel chiral iron phosphate complexes were prepared as catalysts for asymmetric oxidative coupling reactions. These catalysts were applied for the synthesis of enantio-enriched C1- and C2-symmetric BINOLs, in which the 3 and 3¡ä positions are available for chemical modifications. It was proposed that the reaction takes place via an oxidative radical-anion coupling mechanism. A destructive BINOL racemization that competes with the enantioselective oxidative coupling of 2-naphthols was revealed, thereby offering new insights into this highly important reaction.
Reference:&©|160;Narute, Sachin; Parnes, Regev; Toste, F. Dean; Pappo, Doron [Journal of the American Chemical Society, 2016, vol. 138, # 50, p. 16553 - 16560]
GM Chemical Co., Ltd is a professional fine chemical manufacture, integrating development, production and sale. The co***ny was established in 2014, and the registered capital is RMB 1 million. Our R&D center is located in Changsha city, Hunan province, and the sale office is located in Shanghai. Since its inception, we have been specialized in developing and manufacturing benzene substitution(like styrene series), heterocyclic substitution (like crown ether series), boronic acid de |
| Company: |
GM Chemical Co., Ltd
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| Contact: |
Mr. Kimi Xu |
| Address: |
RM 202, NO 1602, West Zhongshan Rd |
| Postcode: |
200235 |
| Tel: |
86-21-80264647 |
| Fax: |
86-21-80264547 |
| E-mail: |
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